Theory of electron transfer processes via chemisorbed intermediates: Part II. Current-potential characteristics

Mishra, A. K. ; Bhattacharjee, B. ; Rangarajan, S. K. (1992) Theory of electron transfer processes via chemisorbed intermediates: Part II. Current-potential characteristics Journal of Electroanalytical Chemistry, 331 (1-2). pp. 801-813. ISSN 0022-0728

Full text not available from this repository.

Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0022-0728(92)85007-P

Abstract

Current-potential characteristics are obtained numerically for a lone-adsorbate-mediated anodic charge transfer at the electrode-solution interface. An increase in the overpotential leads to the appearance of maxima in the anodic current-potential plots instead of the extended activationless region (i.e. a saturation current at large positive overpotentials) predicted by the direct heterogeneous outer-sphere anodic charge transfer process. A detailed analysis of the dependence of current-potential profiles and other kinetic parameters on various system parameters is also presented.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:81219
Deposited On:04 Feb 2012 12:38
Last Modified:04 Feb 2012 12:38

Repository Staff Only: item control page