Dehydrogenation of 2-propanol on doped nickel oxide catalysts

Chakrabarty, D. K. ; Bheema Raju, V. ; Biswas, A. B. (1979) Dehydrogenation of 2-propanol on doped nickel oxide catalysts Reaction Kinetics and Catalysis Letters, 11 (1). pp. 63-69. ISSN 0133-1736

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Official URL: http://www.springerlink.com/content/mg372571x03323...

Related URL: http://dx.doi.org/10.1007/BF02098335

Abstract

Lithium and indium doped nickel oxide samples have been prepared with up to 3 at. % of dopant. The electrical properties of these samples have been studied. All the samples exhibit p-type conductivity which increases with lithium doping and decreases upon doping with indium. Dehydrogenation of 2-propanol on these catalysts increases with the hole concentration in the solid. Desorption of acetone appears to be the rate-determining step. A possible mechanism for the reaction is proposed.

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Deposited On:04 Feb 2012 07:48
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