Lanthanoid chirality as a tool for assignment of f-f transitions. Tb3+ and Tm3+ diglycolate

Karmakar, Bhutnath ; Chatterjee, Prabir K. ; Basu, Samita ; Chowdhury, Mihir (1987) Lanthanoid chirality as a tool for assignment of f-f transitions. Tb3+ and Tm3+ diglycolate Bulletin of the Chemical Society of Japan, 60 (8). pp. 2993-2995. ISSN 0009-2673

Full text not available from this repository.

Official URL: http://www.journalarchive.jst.go.jp/english/jnlabs...

Related URL: http://dx.doi.org/10.1246/bcsj.60.2993

Abstract

Although chiral studies have proved to be handy in the assignment of transitions in biological molecules, organic molecules and transition metal complexes, its potentiality for lanthanoid transition needs to be demonstrated. The paper explores the usefulness of CD studies in the assignment of lanthanoid transitions with two specific chiral single crystals-thulium diglycolate (Tm3+-DG) and terbium diglycolate (Tb3+-DG). It has been shown that chirality can distinguish ΔJ=0, ±1 transition from others. The need for studies under higher resolution has been pointed out.

Item Type:Article
Source:Copyright of this article belongs to Chemical Society of Japan.
ID Code:8085
Deposited On:25 Oct 2010 11:19
Last Modified:03 Feb 2011 10:35

Repository Staff Only: item control page