Catalytic asymmetric transfer hydrogenation of ketones using [Ru(p-cymene)Cl2]2 with chiral amino alcohol ligands

Deshpande, Sudhindra H. ; Kelkar, Ashutosh A. ; Gonnade, Rajesh G. ; Shingote, Savita K. ; Chaudhari, Raghunath V. (2010) Catalytic asymmetric transfer hydrogenation of ketones using [Ru(p-cymene)Cl2]2 with chiral amino alcohol ligands Catalysis Letters, 138 (3-4). pp. 231-238. ISSN 1011-372X

Full text not available from this repository.

Official URL: http://www.springerlink.com/content/n23x413r74k433...

Related URL: http://dx.doi.org/10.1007/s10562-010-0408-y

Abstract

Catalytic asymmetric transfer hydrogenation of aromatic alkyl ketones has been investigated using [Ru(p-cymene)Cl2]2 and new derivatives of β-amino alcohols synthesized from (S)-(-)-lactic acid and mandelic acid as ligands. Chiral secondary alcohols were obtained with good to excellent conversion (60-90%) and moderate to good enantioselectivities (40-86%).

Item Type:Article
Source:Copyright of this article belongs to Springer-Verlag.
Keywords:Asymmetric Transfer Hydrogenation; Ru Catalyst; Ketones; Amino Alcohol Ligand
ID Code:8063
Deposited On:25 Oct 2010 10:13
Last Modified:28 May 2011 09:45

Repository Staff Only: item control page