Synthesis and electrochemical signature of novel norbornyl-ferrocene hybrids

Khan, Faiz Ahmed ; Upadhyay, Sarasij K. (2009) Synthesis and electrochemical signature of novel norbornyl-ferrocene hybrids Synthesis, 2009 (16). pp. 2773-2777. ISSN 0039-7881

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-0029-1217601

Abstract

Novel norbornyl-ferrocene hybrids have been synthesized in excellent yields via Diels-Alder reactions between 1,2,3,4-tetrahalo-5,5-dimethoxycyclopentadiene and vinyl- or acryloylferrocenes. Halogen reduction of vinylferrocene adducts followed by catalytic hydrogenation afforded ferrocenyl-norbornane. Hybrids showed the dependence of the redox potential on the nature of the substituents on the norbornyl moiety.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Diels-Alder Reaction; Ferrocene; Radical Hydrodehalogenation; Reduction; Electrochemical Study
ID Code:80348
Deposited On:31 Jan 2012 14:29
Last Modified:31 Jan 2012 14:29

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