Grover, G. S. ; Chaudhari, R. V. (1989) Liquid phase catalytic oxidation of butene to methyl ethyl ketone: a kinetic study Journal of Molecular Catalysis, 49 (2). pp. 143-151. ISSN 0304-5102
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/030451...
Related URL: http://dx.doi.org/10.1016/0304-5102(89)80046-X
Abstract
The kinetics of oxidation of butene to methyl ethyl ketone was studied using a homogeneous PdCl2-CuCl2 catalyst in aqueous medium. The effect of PdCl2 concentration, butene partial pressure and CuCl2 concentration on the rate of reaction was investigated over a temperature range of 308-358 K, and a rate expression has been proposed. The activation energy of the reaction was found to be 3.022 × 104 J mol-1.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 8006 |
| Deposited On: | 25 Oct 2010 09:43 |
| Last Modified: | 30 May 2011 04:52 |
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