Mn(IV) and Co(III)- complexes of -OH-rich ligands possessing O2N, O3N and O4N cores: syntheses, characterization and crystal structures

Dey, Mishtu ; Rao, Chebrolu P. ; Saarenketo, Pauli K. ; Rissanen, Kari ; Kolehmainen, Erkki ; Guionneau, Philippe (2003) Mn(IV) and Co(III)- complexes of -OH-rich ligands possessing O2N, O3N and O4N cores: syntheses, characterization and crystal structures Polyhedron, 22 (27). pp. 3515-3521. ISSN 0277-5387

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.poly.2003.09.015

Abstract

Mn(IV) and Co(III) complexes of tridentate -OH-rich ligands possessing O2N, O3N and O4N donor sets were synthesized, characterized and their structures were established by single crystal X-ray diffraction, where the binding core is O4N2. In the structurally characterized complexes, the coordination geometry about the metal ion was found to be distorted octahedral.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Manganese(IV) Complex; Cobalt(III) Complex; Crystal Structure; Magnetic Moment; Hydrogen Bonds
ID Code:79217
Deposited On:24 Jan 2012 15:25
Last Modified:19 Apr 2012 06:40

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