Mohan Das, T. ; Rao, Chebrolu P. ; Kolehmainen, Erkki ; Kadam, Ramakant M. ; Sastry, Medury D. (2002) Interaction of metal ions with D-glucobenzothiazoline: isolation and characterization of the resultant products Carbohydrate Research, 337 (4). pp. 289-296. ISSN 0008-6215
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0008-6215(01)00317-2
Abstract
Six different metal-ion complexes of D-glucobenzothiazoline were synthesized and characterized by analytical and spectral techniques. Formation of different types of species (ML and ML2) were observed with Cu2+, Ag+, Cd2+, Hg2+, and Zn2+ ions. Existence of an anomeric mixture in the case of the Cu2+ complex is identified from the EPR spectra, and the results were further supported by the simulated spectra. The structures were proposed based on different studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Benzothiazoline Derivatives; Anomeric Mixture; β Anomer; Levorotatory; Bonding and Structural Group Parameters; Inversion of Conformation; Simulated Spectrum |
| ID Code: | 79169 |
| Deposited On: | 24 Jan 2012 15:23 |
| Last Modified: | 19 Apr 2012 06:00 |
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