Kaiwar, S. P. ; Bandwar, R. P. ; Raghavan, M. S. S. ; Rao, C. P. (1994) Transition metal-saccharide chemistry: synthesis and characterization of some monosaccharide complexes Proceedings of the Indian Academy of Sciences - Chemical Sciences, 106 (3). pp. 743-752. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/106/6/743-7...
Related URL: http://dx.doi.org/10.1007/BF02911106
Abstract
Synthesis and characterization of mononuclear complexes of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) with D-fructose and dinuclear complexes of Cr(III) with D-glucose, D-fructose, and L-sorbose are reported. Cyclic voltammetric studies of these complexes suggest their robustness over a wide pH range. Cr(III)-saccharide complexes are found to affect the structure of pSV2 neo DNA irreversibly.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | First Row Transition-metal Saccharide Complexes; Syntheses and Characterization; Absorption; IR; NMR; EPR Spectroscopies; Magnetic and Electrochemical Studies; Cr(III)-induced DNA Cleavage |
| ID Code: | 79147 |
| Deposited On: | 24 Jan 2012 12:02 |
| Last Modified: | 18 May 2016 21:38 |
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