Transition metal saccharide chemistry: synthesis, spectroscopy, electrochemistry and magnetic studies of chromium(III)-hexose complexes and their in vitro interaction with DNA

Rao, Chebrolu P. ; Kaiwar, Sharada P. ; Srinivasa Raghavan, M. S. (1994) Transition metal saccharide chemistry: synthesis, spectroscopy, electrochemistry and magnetic studies of chromium(III)-hexose complexes and their in vitro interaction with DNA Polyhedron, 13 (12). pp. 1895-1906. ISSN 0277-5387

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0277-5387(94)80013-8

Abstract

Saccharide complexes of CrIII were synthesized via chromate reduction. Hexose monosaccharides such as D-glucose, D-fructose, D-galactose, D-mannose and L-sorbose and some acid derivatives, such as D-galacturonic acid and D-gluconic acid, were used. The final CrIII products were isolated, purified and characterized by various analytical, spectroscopic, magnetic and electrochemical methods. All the products reported here are shown to be dinuclear in nature. The inherent stability and robust nature of these complexes is demonstrated and they are shown to affect the pSV2 neo plasmid (DNA) structure in gel electrophoretic experiments.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:79127
Deposited On:24 Jan 2012 12:02
Last Modified:19 Apr 2012 05:40

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