X-ray, dielectric and high pressure studies on a compound exhibiting ferro-, ferri- and antiferroelectric smectic phases

Shankar Rao, D. ; Krishna Prasad, S. ; Chandrasekhar, S. ; Mery, S. ; Shashidhar, R. (1997) X-ray, dielectric and high pressure studies on a compound exhibiting ferro-, ferri- and antiferroelectric smectic phases Molecular Crystals and Liquid Crystals, 292 . pp. 301-310. ISSN 1058-725X

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Related URL: http://dx.doi.org/10.1080/10587259708031939

Abstract

We report X-ray layer spacing, dielectric constant and high pressure measurements on a compound that exhibits the following sequence of phase transitions: smectic A-ferroelectric smectic C-ferrielectric smectic Cy-antiferroelectric smectic CA -hexatic antiferroelectric smectic IA-crystal K. The pressure-temperature diagram shows two three-phase meeting points, which are topologically consistent with critical end points, and reentrant behavior of the C and C phases as the pressure is varied at constant temperature.

Item Type:Article
Source:Copyright of this article belongs to Taylor and Francis Ltd.
Keywords:Ferroelectric; Ferrielectric; Antiferroelectric; Smectics; X-ray; Dielectric Constant; High Pressure Studies; Pressure Temperature Phase Diagram; Critical End Point
ID Code:7910
Deposited On:25 Oct 2010 09:14
Last Modified:16 May 2016 18:01

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