Rhenium. Part XV. Tetragonal complexes of nickel(II) containing coordinated perrhenate [ReO4]

Chakravorti, Mukul C. ; Sarkar, Mukti B. ; Bharadwaj, Parimal K. (1981) Rhenium. Part XV. Tetragonal complexes of nickel(II) containing coordinated perrhenate [ReO4] Transition Metal Chemistry, 6 (4). pp. 211-214. ISSN 0340-4285

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Official URL: http://www.springerlink.com/content/p898r047870k63...

Related URL: http://dx.doi.org/10.1007/BF00618225

Abstract

The compounds Ni(NH3)4(ReO4)2 and Ni(py)4(ReO4)2 prepared by reacting Ni(ReO4)2 with aqueous ammonia or pyridine, when heated at 150° give Ni(NH3)2(ReO4)2 and Ni(py)2(ReO4)2 respectively. The kinetics of the thermal decomposition of Ni(NH3)2(ReO4)2 has been studied. I.r., Raman and electronic spectra, x-ray powder diffraction and magnetic susceptibility measurements (at different temperatures) of the four compounds indicate that they are tetragonal complexes of NiII containing coordinated perrhenate.

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