Single crystal X-ray structural characterization of [BiX2(S2CNEt2)]Infinity, X=Cl, Br

Bharadwaj, P. K. ; Lee, A. M. ; Skelton, B. W. ; Srinivasan, B. R. ; White, A. H. (1994) Single crystal X-ray structural characterization of [BiX2(S2CNEt2)]Infinity, X=Cl, Br Australian Journal of Chemistry, 47 (2). pp. 405-410. ISSN 0004-9425

Full text not available from this repository.

Official URL: http://www.publish.csiro.au/paper/CH9940405

Related URL: http://dx.doi.org/10.1071/CH9940405

Abstract

Single-crystal room-temperature X-ray structure determinations of the title compounds have been carried out. The two compounds are isomorphous, and isomorphous with the previously determined iodide analogue, being monoclinic, P 21/c, a ≈ 10.0, b ≈ 14.9, c ≈ 7.8 Å , β ≈ 92° , Z = 4 formula units; residuals were 0.037, 0.036 for 2197, 1654 'observed' reflections for X = Cl , Br respectively. As in the iodide, the complexes are infinite polymers, with successive bismuth atoms bridged by the two halides and one sulfur atom of the ligand , which also chelates each bismuth. The structure determination of C5H5NCONEt2]2 [Cl5Bi(NC5H5)], isostructural with its thiocarbamoyl analogue, is also recorded.

Item Type:Article
Source:Copyright of this article belongs to Commonwealth Scientific and Industrial Research Organisation Publishing.
ID Code:78717
Deposited On:23 Jan 2012 03:51
Last Modified:23 Jan 2012 03:51

Repository Staff Only: item control page