Goswami, Sreebrata ; Chakravarty, Akhil R. ; Chakravorty, Animesh (1982) The RuII(OH2)-RuIV(O) couple in a ruthenium complex of 2-(phenylazo)pyridine: homogeneous catalysis of the oxidation of water to dioxygen Journal of the Chemical Society, Chemical Communications, 1982 (22). pp. 1288-1289. ISSN 0022-4936
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1982...
Related URL: http://dx.doi.org/10.1039/C39820001288
Abstract
In acidic solution [RuII(OH2)(py)L2]2+ can be oxidised to [RuIV(O)(py) L2]2+ in a single reversible step (E°298= 1.20V) and the oxidised complex catalyses the dehydorgenation of water to dioxygen in the presence of Ce4+[py=pyridine; L=2-(phenylazo)pyridine].
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 78305 |
| Deposited On: | 19 Jan 2012 06:34 |
| Last Modified: | 19 Jan 2012 06:34 |
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