Seayad, A. ; Kelkar, A. A. ; Chaudhari, R. V. (1998) Carbonylation of p-isobutyl phenylethanol to ibuprofen using palladium catalyst: activity and selectivity studies Studies in Surface Science and Catalysis, 113 . pp. 883-889. ISSN 0167-2991
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S01672...
Related URL: http://dx.doi.org/10.1016/S0167-2991(98)80373-X
Abstract
Activity and selectivity studies on the carbonylation of p-isobutyl phenylethanol using palladium catalyst has been studied in a biphasic system comprising of methyl ethyl ketone as the organic phase and 10% HCl as the aqueous phase, as well as the promoter. The effect of parameters such as catalyst precursor, types of ligand, and ligand to metal ratio were studied at a temperature of 403 K. A plausible catalytic cycle is proposed to explain the observed results.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 7800 |
| Deposited On: | 25 Oct 2010 10:23 |
| Last Modified: | 30 May 2011 04:14 |
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