Dissociation of highly charged N2q+ (q>=2) ions via non-Coulombic potential energy curves

Safvan, C. P. ; Mathur, D. (1994) Dissociation of highly charged N2q+ (q>=2) ions via non-Coulombic potential energy curves Journal of Physics B: Atomic, Molecular and Optical Physics, 27 (17). p. 4073. ISSN 0953-4075

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Official URL: http://iopscience.iop.org/0953-4075/27/17/028

Related URL: http://dx.doi.org/10.1088/0953-4075/27/17/028

Abstract

The kinetic energies released (KER) upon dissociation of N2q+ (q=2-10) ions are investigated by means of large scale, all-electron, ab initio, configuration interaction molecular orbital calculations. Results indicate that dissociation via non-Coulombic potential energy curves of N2q+ ions yields lower values of KER than would be expected from purely Coulombic considerations due to the significance of electronic charge density distributions in the internuclear region.

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