Solvation dynamics of 4-aminophthalimide in dioxane-water mixture

Mukherjee, Saptarshi ; Sahu, Kalyanasis ; Roy, Durba ; Mondal, Sudip Kumar ; Bhattacharyya, Kankan (2004) Solvation dynamics of 4-aminophthalimide in dioxane-water mixture Chemical Physics Letters, 384 (1-3). pp. 128-133. ISSN 0009-2614

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.cplett.2003.11.098

Abstract

Solvation dynamics of 4-aminophthalimide (4-AP) in dioxane-water mixtures display a slow component of 350-500 ps. This is attributed to transient dioxane-water clusters and rupture of water-dioxane hydrogen bond. A detailed analysis indicates that there is no preferential solvation of 4-AP in dioxane-water mixture. The solvent shift of the emission maximum of 4-AP in a solution is shown to be controlled by hydrogen bond parameters of the solvent.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:77152
Deposited On:10 Jan 2012 07:52
Last Modified:10 Jan 2012 07:52

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