Parkash, Ram ; Ahluwalia, S. C. ; Sud, S. C. ; Sahni, R. N. ; Paul, R. C. (1981) Heats of solution and neutralization of Lewis acids and bases in acetic anhydride Monatshefte für Chemie / Chemical Monthly, 112 (6-7). pp. 707-711. ISSN 0026-9247
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Official URL: http://www.springerlink.com/content/x85h432121rm02...
Related URL: http://dx.doi.org/10.1007/BF00899773
Abstract
Heats solution of someLewis acids and bases in acetic anhydride have been determined and the following order of their relative strengths is proposed: SbCl5>SO3>SnCl4>TiCl4>AsCl3 and piperidine> n-butylamine>potassium acetate>sodium acetate ≈ α-picoline>quinoline. Heats neutralization of theseLewis acids and bases in acetic anhydride suggest that the major enthalpy change in these neutralization reactions is due to the combination of a proton and the (CH2COOCOCH3)- ion, resulting in the formation of acetic anhydride.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer. |
| Keywords: | Calorimetry; Thermodynamics |
| ID Code: | 77114 |
| Deposited On: | 09 Jan 2012 14:29 |
| Last Modified: | 09 Jan 2012 14:29 |
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