Parkash, Ram ; Ahluwalia, S. C. ; Paul, R. C. (1984) Heats of solution and neutralization of protonic acids and bases in ethanol Monatshefte für Chemie / Chemical Monthly, 115 (2). pp. 135-140. ISSN 0026-9247
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Official URL: http://www.springerlink.com/content/r13800kg481614...
Related URL: http://dx.doi.org/10.1007/BF00798403
Abstract
Heats of solution of several protonic acids and bases in ethanol have been measured and the following order of their relative strengths is inferred: HSO3F > H2S2O7 > H2SO4 > HCOOH and sodium ethoxide > potassium ethoxide > piperidine > n-butylamine > benzylamine > morpholine > α-picoline > pyridine > quinoline. Major enthalpy change in the neutralization reactions is attributed to the combination of ethoxonium and ethoxy ions resulting in the formation of ethanol.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer. |
| Keywords: | Calorimetry; Thermodynamics |
| ID Code: | 77113 |
| Deposited On: | 09 Jan 2012 14:29 |
| Last Modified: | 09 Jan 2012 14:29 |
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