Some compounds of iron(III) with bidentate bases

Paul, Ram C. ; Narula, Ramesh C. ; Vasisht, Sham K. (1977) Some compounds of iron(III) with bidentate bases Transition Metal Chemistry, 2 (1). pp. 152-154. ISSN 0340-4285

Full text not available from this repository.

Official URL:

Related URL:


The iron(III) compound, FeCl(OH)(MeCO2) · MeCO2H · 0.5 H2O, (1), interacts with the sample bidentate ligand, 2,2-bipyridyl (bipy), to form an aduct, Fe2Cl2(OH)2(MeCO2)2 · (bipy). By the loss of protons, anthranilic (anthH) and salicylic (salH2) acids behave as uninegative charged ligands to give FeCl(anth)2 · H2O and FcCl(salH)2 · H2O, respectively. The former decomposes on heatingin vacuo to form Fe2O(anth)4 while the latter yields Fe2O(sal)2. Acetylacetone (acacH) and 8-hydroxyquinoline (quinH) give FeCl(acac)2 and FeCl(quin)2 · (quinH). The latter desolvates at 140°/10-4 torr to form FeCl(quin)2. l.r. spectra, thermal decomposition, molar conductance and magnetic susceptibility studies at room temperature have been used to characterize these compounds.

Item Type:Article
Source:Copyright of this article belongs to Springer.
ID Code:77103
Deposited On:09 Jan 2012 14:28
Last Modified:09 Jan 2012 14:28

Repository Staff Only: item control page