Lewis base behaviour of diphenyl telluroxide

Paul, Ram Chand ; Chadha, Raj K. ; Bhandal, B. S. ; Singh, Gurdev (1981) Lewis base behaviour of diphenyl telluroxide Inorganica Chimica Acta, 52 . pp. 125-128. ISSN 0020-1693

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0020-1693(00)88585-0


Diphenyl telluroxide, (DPTO), reacts with Sn(IV), Ti(IV) and Sb(V) chlorides to give diphenyltellurium dichloride, but with organotellurium trichlorides (R = Me, pMeOPh, pPhOPh) it forms 2:1 addition products. These products have been characterised by elemental analysis and IR spectra. The Te O vibrations in diaryl telluroxides have been assigned by comparing the IR spectra of diaryl telluroxides, diaryl tellurides and bis(diaryltellurium chloride)oxides (R = Ph, pMeOPh and pMePh).

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