Behaviour of metal halides in disulphuric acid. II

Paul, Ram Chand ; Puri, J. K. ; Kapila, V. P. ; Malhotra, K. C. (1972) Behaviour of metal halides in disulphuric acid. II Journal of Inorganic and Nuclear Chemistry, 34 (7). pp. 2141-2151. ISSN 0022-1902

Full text not available from this repository.

Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0022-1902(72)80146-5

Abstract

Tetrachlorides of tin and titanium form H2[Sn(HSO4)6] and H2[Ti(HSO4)6] respectively in disulphuric acid. The compounds behave as weak acids in this system. On the other hand, boron trichloride, antimony pentafluoride and chloride form H[B(HSO4)4], H[SbF2(SO3F)4] and H[SbCl2-(SO3Cl)4] respectively, all of which behave as strong acids in disulphuric acid. But bismuth, tin and lead chlorides and thalium mono and trichlorides behave as bases.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:77074
Deposited On:09 Jan 2012 14:22
Last Modified:09 Jan 2012 14:22

Repository Staff Only: item control page