Behaviour of some vanadium(V) and chromium(VI) compounds in disulphuric acid

Paul, Ram Chand ; Puri, J. K. ; Malhotra, K. C. (1971) Behaviour of some vanadium(V) and chromium(VI) compounds in disulphuric acid Journal of Inorganic and Nuclear Chemistry, 33 (12). pp. 4191-4198. ISSN 0022-1902

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0022-1902(71)80520-1

Abstract

Vanadium pentoxide, vanadyl chloride and ammonium metavanadate form H[VO(HSO4)4] when dissolved in disulphuric acid. This compound behaves as a non-electrolyte in the acid. At higher concentrations, there is indication of its polymerisation. Chromyl chloride, potassium chromate and dichromate form CrO2(HSO4)2 when dissolved in disulphuric acid. There is also indication of the polymerisation of CrO2(HSO4)2 at higher concentration.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:77069
Deposited On:09 Jan 2012 14:22
Last Modified:09 Jan 2012 14:22

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