Bromine cyanide as titrimetric oxidant in non-aqueous media

Paul, Ram Chand ; Chauman, Raj Kumar ; Parkash, Ram (1974) Bromine cyanide as titrimetric oxidant in non-aqueous media Talanta, 21 (6). pp. 663-667. ISSN 0039-9140

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Bromine cyanide has been used for the potentiometric determination of sulphide, sulphite, thiocyanate, iodide, tin(II), arsenic(III),hydrazine hydrate, phenylhydrazine, 1,1-methylphenyldrazine and chloralhydrazine in glacial acetic acid and 1:1 acetic acid-acetic anhydride mixture, of thiourea, ethylthiourea, isopropylthiourea, benzylthiourea, α-phenylthiourea and o-tolythiourea in methanol, and of sodium methyl-, ethyl-,dimethyl-, diehtyl- and isopropyldithiocarbamates in ehtanol and acetonitrile media. The behaviour of bromine cyanide in these non-aqueous solvents has been compared with its behaviour in aqueous medium and with that of iodine cyanide in these non-aqueous solvents.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:77034
Deposited On:09 Jan 2012 14:24
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