Ranganathan, Subramania ; Ranganathan, Darshan ; Bhattacharyya, Dipti (1991) The transformation of histidine side chain to non-coded asparagines Tetrahedron Letters, 32 (40). pp. 5615-5618. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0040-4039(91)80099-R
Abstract
The transformation of the histidine side chain to that of Nω-carbamoyl asparagine, Nω-formyl asparagine, Nω-benzoyl asparagine, β-cyano alanine and aspartic acid has been described, involving as the primary step, the Ru(VIII) mediated scission of imidizole 4,5-π bond. Products arising from the rupture of each of the 5 bonds of the imidazole ring of His side chain make their appearance via key intermediate generated by the 4,5-π bond scission with Ru(VIII).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 76829 |
| Deposited On: | 07 Jan 2012 08:45 |
| Last Modified: | 15 Jul 2012 10:21 |
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