Jayasree, S. ; Seayad, A. ; Chaudhari, R. V. (2000) Novel palladium(II) complex containing a chelating anionic N-O ligand: efficient carbonylation catalyst Organic Letters, 2 (2). pp. 203-206. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol9912884
Related URL: http://dx.doi.org/10.1021/ol9912884
Abstract
A novel palladium(II) complex containing chelating anionic pyridine-2-carboxylato and labile tosylato ligands is a highly efficient catalyst for the carbonylation of organic alcohols and olefins to carboxylic acids/esters. Carbonylation of primary, secondary, and tertiary alcohols as well as linear and functionalized terminal olefins was studied. In all cases remarkable activity and selectivity were observed. The catalyst is stable under reaction conditions even in the absence of excess phosphine ligands.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 7591 |
| Deposited On: | 25 Oct 2010 11:05 |
| Last Modified: | 30 May 2011 03:52 |
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