An unusual observation in the rhodium carbenoids: [1,4]-migration in the sugar-derived α-diazo-β-ketoesters

Desai, Vijaya N. ; Saha, Nabendu N. ; Dhavale, Dilip D. (2000) An unusual observation in the rhodium carbenoids: [1,4]-migration in the sugar-derived α-diazo-β-ketoesters Journal of the Chemical Society, Perkin Transactions 1, 1 (2). pp. 147-151. ISSN 0300-922X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2000...

Related URL: http://dx.doi.org/10.1039/A908453C

Abstract

In competition with [1,2]-migration, [2,3]-sigmatropic rearrangement and C-H insertion, product formation via an unusual [1,4]-migration is also found to be a prominent process in the rhodium carbenoids derived from sugar α-diazo-β-keto esters 2a-d.

Item Type:Article
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ID Code:75360
Deposited On:22 Dec 2011 13:10
Last Modified:22 Dec 2011 13:10

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