First organotin complex of a phosphonic diamide RP(O)(NHR)2

Murugavel, Ramaswamy ; Pothiraja, Ramasamy ; Shanmugan, Swaminathan ; Singh, Namrata ; Butcher, Ray J. (2007) First organotin complex of a phosphonic diamide RP(O)(NHR)2 Journal of Organometallic Chemistry, 692 (10). pp. 1920-1923. ISSN 0022-328X

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.jorganchem.2006.12.044

Abstract

Diorganotin dichloride-phosphonic diamide complex, [Ph2SnCl2(tBuP(O)(NHiPr)2)2] (1), is prepared by the addition of two equivalents of tBuP(O)(NHiPr)2 to one equivalents of Ph2SnCl2 either in the presence or absence of triethylamine. Compound 1 is a rare example of an all-trans SnA2B2C2 complex that contains H-bonded six-membered rings which are made up of six different main group elements.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Phosphonamide; X-ray Structure; Organotin Chemistry
ID Code:75173
Deposited On:22 Dec 2011 03:23
Last Modified:22 Dec 2011 03:23

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