Murugavel, Ramaswamy ; Sathiyendiran, Malaichamy (2001) Di-tert-butylphosphate complexes of Mn(II) and Cu(II) as single-source precursors for metal phosphate materials Chemistry Letters, 30 (1). p. 84. ISSN 0366-7022
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Official URL: http://www.jstage.jst.go.jp/article/cl/30/1/30_84/...
Related URL: http://dx.doi.org/10.1246/cl.2001.84
Abstract
Octahedral Mn(II) and Cu(II) di-tert-butylphosphate (L) complexes [ML2(imz)4] have been synthesized and characterized using IR, UV-vis, luminescence, and EPR spectroscopy and single crystal X-ray diffraction studies. Thermal decomposition of both the complexes (probed by TGA, DTA, and DSC) indicate stepwise elimination of iso-butene, imidazole and water to finally yield the respective ceramic materials Mn(PO3)2 or Cu(PO3)2.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Chemical Society of Japan. |
| ID Code: | 75163 |
| Deposited On: | 22 Dec 2011 03:17 |
| Last Modified: | 22 Dec 2011 03:17 |
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