An efficient synthetic route to primary and secondary condensation products of silanetriols starting from (arylamino)trichlorosilanes

Murugavel, Ramaswamy ; Bottcher, Peter ; Voigt, Andreas ; Walawalkar, Mrinalini G. ; Roesky, Herbert W. ; Parisini, Emilio ; Teichert, Markus ; Noltemeyer, Mathias (1996) An efficient synthetic route to primary and secondary condensation products of silanetriols starting from (arylamino)trichlorosilanes Chemical Communications, 1996 (21). pp. 2417-2418. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1996...

Related URL: http://dx.doi.org/10.1039/CC9960002417

Abstract

Stoichiometry dependent hydrolysis of (arylamino)-silyltrichlorides using anhydrous N2H4 as the HCl acceptor and dehydrating agent leads to the formation of the primary and secondary condensation products of silanetriols, tetrahydroxydisiloxanes [Ar(SiMe3)NSi(OH)2]2O and cyclotrihydroxytrisiloxanes [Ar(SiMe3)NSi(OH)O]3, respectively.

Item Type:Article
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