Chandrasekhar, J. ; Chandra Kumar, N. ; Subramanian, S. (1975) EPR of manganese(II) in tetramethylammonium tetrachlorozincate(II) Journal of Magnetic Resonance (1969), 18 (1). pp. 129-138. ISSN 0022-2364
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/002223...
Related URL: http://dx.doi.org/10.1016/0022-2364(75)90231-0
Abstract
EPR spectra of Mn(II) in the tetrahedral crystal field of chloride ions in single crystals of tetramethylammoniumtetrachlorozincate(II) is reported. The presence of two magnetically distinct sites has been correlated with the host lattice ZnCl42- local geometry. The spin-Hamiltonian parameters for this high-spin d5 system are g = 2.0023; A = -82.0 G, B =-80 G; A=-10.7 G; D= +130.8G and F=+4.8G. The absolute sign of the cubic field splitting parameter a is discussed. Two low temperature phase transitions have been detected.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 7484 |
| Deposited On: | 25 Oct 2010 11:25 |
| Last Modified: | 30 May 2011 07:05 |
Repository Staff Only: item control page
