Wide-line NMR studies on organic and biomolecules: Part IX- PMR study of some acetates and related compounds

Jagannathan, N. R. ; Srinivasan, R. (1984) Wide-line NMR studies on organic and biomolecules: Part IX- PMR study of some acetates and related compounds Indian Journal of Pure & Applied Physics, 22 (8). pp. 484-499. ISSN 0019-5596

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Abstract

The wide-line PMR studies of some acetates and related compounds are reported. These are acetates of mercury, calcium, aluminum and barium in the unhydrated forms and of lead, magnesium, cadmium, zinc, manganese, cobalt, nickel and copper in the hydrated forms. In addition, studies on l-naphthalene acetic acid, 2-naphthyloxy acetic acid and L-ascorbic acid are also reported. In all the acetates, methyl group reorientation is present even at low temperature. In addition, for the hydrated acetates flip motion of the water protons is present. The lattice is essentially rigid in the case of 1-naphthalene acetic acid and 2-naphthyloxy acetic acid and ascorbic acid.

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