On the quantum corrections to the radial distribution function and to the thermodynamic properties of fluids. II

Singh, Y. ; Ram, J. (1974) On the quantum corrections to the radial distribution function and to the thermodynamic properties of fluids. II Molecular Physics, 28 (1). pp. 197-208. ISSN 0026-8976

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0026897...

Related URL: http://dx.doi.org/10.1080/00268977400101631

Abstract

The grand canonical ensemble is used to derive the first quantum correction (FQC) to the radial distribution function (RDF) for a fluid whose molecules interact with a potential which is an analytic function of distance. The low-order cluster integrals appearing in the density expansion of the RDF are evaluated on the Lennard-Jones (12-6) potential. The FQC to the isothermal compressibility and to the equation of state is discussed.

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