Electrical transport properties of a supramolecular assembly

Pan, Arvind ; Ghosh, Aswini ; Chowdhury, Shubhamoy ; Datta, Dipankar (2001) Electrical transport properties of a supramolecular assembly Inorganic Chemistry Communications, 4 (9). pp. 507-510. ISSN 1387-7003

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S1387-7003(01)00264-7


The direct current conductivity of the urea–[CuIL2]PF6 supramolecular assembly (1) has been measured in the temperature range 24-118°C. It is found that 1 behaves as a semiconductor in 24-33°C, as a metal in 33-63°C and again as a semiconductor in 63-118°C. Such transitions between semiconductor and metal like behaviour have not been observed earlier in the clathrates.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Clathrates; Supramolecule; Electrical Conductivity; Copper(I) Complexes; Urea
ID Code:72848
Deposited On:29 Nov 2011 13:01
Last Modified:29 Nov 2011 13:01

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