'Core and sheath' structure of a TTF complex forming a square grid

Jayanty, Subbalakshmi ; Radhakrishnan, T. P. (1999) 'Core and sheath' structure of a TTF complex forming a square grid Journal of Materials Chemistry, 9 (8). pp. 1707-1711. ISSN 0959-9428

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Official URL: http://xlink.rsc.org/?doi=a901661i

Related URL: http://dx.doi.org/10.1039/A901661

Abstract

The crystal structure of the pentakis(methoxycarbonyl)cyclopentadienide salt of tetrathiafulvalene is reported. It is found to have a novel two-dimensional structure in the form of a square grid. The grid is formed out of TTF stacks running in orthogonal directions; the TTF stacks form a core structure with the counterions providing a sheath around them. DC conductivity measurements on single crystals reveal the anisotropy expected of this unusual two-dimensional packing motif.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:72563
Deposited On:29 Nov 2011 04:13
Last Modified:29 Nov 2011 04:13

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