Kesavan, Venkitasamy ; Sivanand, Pennadam S. ; Chandrasekaran, Srinivasan ; Koltypin, Yuri ; Gedanken, Aharon (1999) Catalytic aerobic oxidation of cycloalkanes with nanostructured amorphous metals and alloys Angewandte Chemie International Edition, 38 (23). pp. 3521-3523. ISSN 1433-7851
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Official URL: http://www3.interscience.wiley.com/journal/6750175...
Related URL: http://dx.doi.org/10.1002/(SICI)1521-3773(19991203)38
Abstract
Under mild conditions (40 atm O2, 28°C, 10-15 h), an efficient aerobic oxidation of cycloalkanes to cycloalkanols can be achieved using nanostructured amorphous metals such as Fe and Co and an amorphous alloy like Fe20Ni80 as catalysts. For example, cyclohexane is oxidized to cyclohexanol with 32-41% conversion, while 1-adamantanol is formed from adamantane with 52-57 % conversion.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Catalysts; C-H Activation; Nanostructures; Oxidations |
| ID Code: | 7229 |
| Deposited On: | 25 Oct 2010 12:06 |
| Last Modified: | 01 Feb 2011 11:38 |
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