Extrinsic circular dichroic effects in retinoates

Singh, Anil K. (1986) Extrinsic circular dichroic effects in retinoates Journal of the Chemical Society, Perkin Transactions 2, 2 (5). pp. 635-636. ISSN 0300-9580

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1986...

Related URL: http://dx.doi.org/10.1039/P29860000635


(−)-1-Phenylethyl retinoate shows a Cotton effect with c.d. bands at 360, 245, and 215 nm, whereas (+)-octan-2-yl retinoate has no such band in the 220-450 nm region. This can be explained either in terms of a dipole-dipole interaction between the phenyl and retinylidene moieties or in terms of the dissymmetric environment of the polyene. The results are pertinent to the origin of c.d. in rhodopsins.

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