Retinylidene Schiff-base protonation in surfactant-solubilized water pools in heptane

Singh, Anil K. ; Sandorfy, Camille ; Fendler, Janos H. (1990) Retinylidene Schiff-base protonation in surfactant-solubilized water pools in heptane Journal of the Chemical Society - Series Chemical Communications, 1990 (3). pp. 233-234. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1990...

Related URL: http://dx.doi.org/10.1039/C39900000233

Abstract

All-trans-N-retinylidene-n-butylamine (4) and its 3-chloropropionic acid (CPA) protonated analogue (5) remained stable in sodium bis(2-ethylhexyl) sulphosuccinate, reversed-micelle-solubilized water pools in heptane, and the extent to which (4) protonated depended on the [CPA] to [(4)] ratio and on the amount of solubilized water; hence, this system mimicked the behaviour of rhodopsins.

Item Type:Article
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ID Code:72104
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