Fluorine chemical shift tensors in substituted fluorobenzenes using cross correlations in NMR relaxation

Dorai, Kavita ; Anil Kumar, (2001) Fluorine chemical shift tensors in substituted fluorobenzenes using cross correlations in NMR relaxation Chemical Physics Letters, 335 (3-4). pp. 176-182. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00092...

Related URL: http://dx.doi.org/10.1016/S0009-2614(00)01293-8

Abstract

The effect of cross correlations between the chemical shift anisotropy of fluorine and its dipolar interaction with nearby protons has been investigated via multi-spin longitudinal relaxation studies in fluorinated benzenes. Experiments have been performed on four different fluorinated benzenes. Significant variations in the value/orientation of the chemical shift anisotropy tensors of fluorine have been observed as a function of substitution.

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ID Code:719
Deposited On:25 Sep 2010 04:59
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