Chandrasekhar, Jayaraman ; Kahn, Richard A. ; Schleyer, Paul von Rague (1982) The preferred structure of C2H-2 Chemical Physics Letters, 85 (5-6). pp. 493-495. ISSN 0009-2614
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(82)80343-6
Abstract
Alternative structures for C2H-2 have been investigated by ab initio calculations using augmented basis sets. Results indicate both cis bent and trans bent acetylene-like HCCH- alternatives are unstable towards electron loss. The electron affinity of vinylidene, H2C=C:, is found to be positive. Hence, the resulting anion, H2C=C-, is indicated to be the observed long-lived C2H-2 species.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 7185 |
| Deposited On: | 25 Oct 2010 12:20 |
| Last Modified: | 05 Feb 2011 10:05 |
Repository Staff Only: item control page
