Synthesis of ethyl arylacetates by means of Friedel-Crafts reactions of aromatic compounds with ethyl α-chloro-α-(ethylthio) acetate catalysed by ytterbium triflate

Sinha, Surajit ; Mandal, Bhubaneswar ; Chandrasekaran, Srinivasan (2000) Synthesis of ethyl arylacetates by means of Friedel-Crafts reactions of aromatic compounds with ethyl α-chloro-α-(ethylthio) acetate catalysed by ytterbium triflate Tetrahedron Letters, 41 (47). pp. 9109-9112. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)01626-9

Abstract

An efficient Friedel-Crafts alkylation of aromatic compounds with ethyl α-chloro-α-(ethylthio)acetate catalysed by ytterbium triflate, followed by desulfurisation of the product provides a convenient methodology for the synthesis of ethyl arylacetates of aromatic and heteroaromatic compounds.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Catalysis; Friedel-crafts Reaction; Lanthanides; Substitution
ID Code:7182
Deposited On:25 Oct 2010 12:20
Last Modified:01 Feb 2011 11:12

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