Ring size effects on 1,2-shifts in carbocations

Chandrasekhar, Jayaraman ; Schleyer, Paul von Rague (1979) Ring size effects on 1,2-shifts in carbocations Tetrahedron Letters, 20 (42). pp. 4057-4060. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)86502-3


1,2-Hydride shift barriers in classical carbenium ions increase with decreasing ring size; this can be attributed to the increased strain of the H bridged structures in the small rings.

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