Ravikumar, K. S. ; Baskaran, Sundarababu ; Chandrasekaran, Srinivasan (1993) Diisopropoxytitanium(III) tetrahydroborate: a highly useful reagent for the remarkably selective 1,2-reduction of α,β-unsaturated carbonyl compounds Journal of Organic Chemistry, 58 (22). pp. 5981-5982. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo00074a026
Related URL: http://dx.doi.org/10.1021/jo00074a026
Abstract
Diisopropoxytitanium(III) tetrahydroborate formed by the reaction of diisopropoxytitanium dichloride and benzyltriethylammonium borohydride (1:2) reacts with a variety of α,β-usaturated carbonyl compounds in dichloromethane (-20°C) very readily to yield exclusively the corresponding allylic alcohols in excellent yields.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 7155 |
| Deposited On: | 25 Oct 2010 12:27 |
| Last Modified: | 03 Feb 2011 06:30 |
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