Chemoselective deoxygenation of nitrones and N-oxides with tetrathiomolybdate

Ilankumaran, Palanichamy ; Chandrasekaran, Srinivasan (1995) Chemoselective deoxygenation of nitrones and N-oxides with tetrathiomolybdate Tetrahedron Letters, 36 (27). pp. 4881-4882. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...

Related URL: http://dx.doi.org/10.1016/0040-4039(95)00875-D

Abstract

Reaction of nitrones and N-oxides with benzyltriethylammonium tetrathiomolybdate 1̲ in acetonitrile (25°C) yielded the corresponding imines and amines in good yields. Sulfoxides and azoxy benzenes are unaffected.

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