Andrade, Juan G. ; Clark, Timothy ; Chandrasekhar, Jayaraman ; Schleyer, Paul von Rague (1981) Alternative mechanisms for cyanide anion exchange with acetonitrile Tetrahedron Letters, 22 (31). pp. 2957-2960. ISSN 0040-4039
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4039(01)81798-6
Abstract
Mechanisms for the recently observed exchange of cyanide anion in acetonitrile have been investigated by means of semi-empirical MNDO molecular orbital calculations. A prototropic type mechanism via a cyclopropane intermediate is the most likely candidate. The previously proposed concerted migration is indicated to be the least favourable reaction pathway.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 7132 |
| Deposited On: | 25 Oct 2010 12:31 |
| Last Modified: | 05 Feb 2011 10:37 |
Repository Staff Only: item control page
