A facile reductive cleavage of allylic and benzylic esters with low valent titanium reagents

Satyanarayana, K. ; Chidambaram, N. ; Chandrasekaran, S. (1989) A facile reductive cleavage of allylic and benzylic esters with low valent titanium reagents Synthetic Communications, 19 (11-12). pp. 2159-2166. ISSN 0039-7911

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Related URL: http://dx.doi.org/10.1080/00397918908052611

Abstract

The reductive cleavage of allylic and benaylic esters 1a-g̲ with titanium(II) reagent derived from Mg/Hg-TiCl yielded the corresponding acids 3a-g̲ and dimeric hydro 4 carbons 2a-g̲ under mild reaction conditions.

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Deposited On:25 Oct 2010 12:39
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