Rearrangements of bicyclic-δ-hydroxy-α,β-enones—IV : base catalysed rearrangements of some bicyclic-α-substituted-δ-hydroxy-α,β-enones

Swaminathan, S. ; Srinivasan, K. G. ; Venkataramani, P. S. (1970) Rearrangements of bicyclic-δ-hydroxy-α,β-enones—IV : base catalysed rearrangements of some bicyclic-α-substituted-δ-hydroxy-α,β-enones Tetrahedron, 26 (5). pp. 1453-1461. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)92974-6

Abstract

The hydroxy enones 5a, 5b, 5c, 4d, 4a and 4b rearrange when treated with aqueous alkali to the diones 6a, 6b, 8 and 13 and acids 9 and 12 respectively. The diones 2 and 6a are also formed by thermal rearrangement of enones 1a and 5a.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:70773
Deposited On:21 Nov 2011 05:25
Last Modified:21 Nov 2011 05:25

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