Sathyamoorthi, G. ; Thangaraj, K. ; Srinivasan, P. C. ; Swaminathan, S. (1990) A new synthesis of angularly substituted bicyclic systems via an anionic oxy-cope rearrangement Tetrahedron, 46 (10). pp. 3559-3568. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)81524-6
Abstract
A general synthesis of trans bicyclic carbinols with an angular methyl substituent using the anionic oxy-Cope rearrangement is reported. The carbinols 13a̲ ,13b̲ ,14a̲ ,14b̲ and 15̲ furnish the bicyclic carbinols 16a̲, 16b̲, 17a̲, 17b̲ and 18̲ when treated with potassium hydride in 1,2-dimethoxyethane.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 70760 |
| Deposited On: | 21 Nov 2011 05:22 |
| Last Modified: | 21 Nov 2011 05:22 |
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