Venkataramani, P. S. ; John, J. P. ; Ramakrishnan, V. T. ; Swaminathan, S. (1966) Stereospecific reductions of 1α-ethynyl-1β-hydroxy-5-oxo-7a-methyl-2,3,5,6,7,7a-hexahydro-indene and some Diels alder condensations with cis-3-vinyl-6-oxo-3a-methyl-3a,4,5,6,7,7a-hexahydroindene Tetrahedron, 22 (7). pp. 2021-2027. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)82121-9
Abstract
The ethynyl compound (I) named in the title and some of its derivatives have been catalytically reduced with lithium-ammonia and with sodium borohydride. A high degree of stereospecificity is observed in these reductions. The vinyl alcohol (V) was dehydrated to the diene (XV) which condensed readily with p-benzoquinone and maleic anhydride.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 70758 |
| Deposited On: | 21 Nov 2011 05:27 |
| Last Modified: | 21 Nov 2011 05:27 |
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