Sivaram, Swaminathan ; Upadhyay, Vinod Kumar (1992) Synthesis of high-cis-polybutadiene using cobalt (II)-2-ethylhexoate modified triethylaluminum catalyst Journal of Macromolecular Science, Part A, 29 (Suppl.1). pp. 13-19. ISSN 1060-1325
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Official URL: http://www.tandfonline.com/doi/abs/10.1080/1010132...
Related URL: http://dx.doi.org/10.1080/10101329208054559
Abstract
Pretreatment of triethylaluminum with active chlorine bearing adjuvants led to the formation of an active cocatalyst for 1,3-butadiene polymerization to high-cis-polybutadiene using cobalt (II)-2-ethyl hexoate as catalyst. The features of the polymerization, namely, conversion, molecular weight and micro-structure were found to depend on the Cl/Al ratio. Polymerization behaviour in both benezene and benzene-butene-1 mixture were similar and closely resembled that observed with the conventional cobalt(II)-2-ethylhexoate - diethylaluminum chloride catalyst system.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Group. |
| ID Code: | 70058 |
| Deposited On: | 18 Nov 2011 12:53 |
| Last Modified: | 18 Nov 2011 12:53 |
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